Progress in Raman Spectroscopy and Reduction of Carbon Dioxide

Adil Emin; Tursunay Mamtimin

doi:doi:10.11648/j.sjc.20210906.12

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Progress in Raman Spectroscopy and Reduction of Carbon Dioxide

Adil Emin, Tursunay Mamtimin

Published in Science Journal of Chemistry (Volume 9, Issue 6)

Received: 8 October 2021 Accepted: 25 October 2021 Published: 23 November 2021

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Abstract

The metal catalyst has good electrical conductivity, is simple to prepare and easy to be applied in practice. It is currently the most in-depth researched catalyst for electrochemical reduction of carbon dioxide. In recent decades, metals such as copper, cobalt, tin, and gold have been used as electrode catalysts for reducing carbon dioxide. From the perspective of the reduction mechanism of carbon dioxide, it is generally believed that the formation of C intermediate is the rate-determining step of the entire reduction reaction. One of the main functions of metal catalysts is to enable the corresponding reaction intermediates to exist stably, thereby improving the energy efficiency of the reaction. According to the combination with different intermediates and the different products obtained, the metal electrode catalysts can be divided into three categories. In this paper, the current research status of electrocatalytic and photocatalytic reduction of carbon dioxide and carbon dioxide under Raman spectroscopy are introduced. Also elaborate, the Raman spectroscopic characterization of carbon dioxide has been introduced in this paper with emphasis on the changes of Fermi resonance peaks of CO₂ with temperature and pressure. The advantages and disadvantages of using metal and metal complexes, carbon materials, composite materials and MOF materials to reduce CO₂ are introduced. The method was improved, and finally focused on the core issues of improving reactivity and product selectivity, and analyzed the shortcomings of current electrocatalytic processes extended to large-scale production applications from surface engineering, chemical modification, nano or composite materials. There are other ways to improve the activity of the catalyst from these aspects, as well as the prospects for future research.

Published in	Science Journal of Chemistry (Volume 9, Issue 6)
DOI	10.11648/j.sjc.20210906.12
Page(s)	135-144
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2021. Published by Science Publishing Group

Keywords

Carbon Dioxide, Electrocatalytic Reduction, Photocatalytic, Raman Scattering

References

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Adil Emin, Tursunay Mamtimin. (2021). Progress in Raman Spectroscopy and Reduction of Carbon Dioxide. Science Journal of Chemistry, 9(6), 135-144. https://doi.org/10.11648/j.sjc.20210906.12

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Adil Emin; Tursunay Mamtimin. Progress in Raman Spectroscopy and Reduction of Carbon Dioxide. Sci. J. Chem. 2021, 9(6), 135-144. doi: 10.11648/j.sjc.20210906.12

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Adil Emin, Tursunay Mamtimin. Progress in Raman Spectroscopy and Reduction of Carbon Dioxide. Sci J Chem. 2021;9(6):135-144. doi: 10.11648/j.sjc.20210906.12

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@article{10.11648/j.sjc.20210906.12,
  author = {Adil Emin and Tursunay Mamtimin},
  title = {Progress in Raman Spectroscopy and Reduction of Carbon Dioxide},
  journal = {Science Journal of Chemistry},
  volume = {9},
  number = {6},
  pages = {135-144},
  doi = {10.11648/j.sjc.20210906.12},
  url = {https://doi.org/10.11648/j.sjc.20210906.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.sjc.20210906.12},
  abstract = {The metal catalyst has good electrical conductivity, is simple to prepare and easy to be applied in practice. It is currently the most in-depth researched catalyst for electrochemical reduction of carbon dioxide. In recent decades, metals such as copper, cobalt, tin, and gold have been used as electrode catalysts for reducing carbon dioxide. From the perspective of the reduction mechanism of carbon dioxide, it is generally believed that the formation of C intermediate is the rate-determining step of the entire reduction reaction. One of the main functions of metal catalysts is to enable the corresponding reaction intermediates to exist stably, thereby improving the energy efficiency of the reaction. According to the combination with different intermediates and the different products obtained, the metal electrode catalysts can be divided into three categories. In this paper, the current research status of electrocatalytic and photocatalytic reduction of carbon dioxide and carbon dioxide under Raman spectroscopy are introduced. Also elaborate, the Raman spectroscopic characterization of carbon dioxide has been introduced in this paper with emphasis on the changes of Fermi resonance peaks of CO2 with temperature and pressure. The advantages and disadvantages of using metal and metal complexes, carbon materials, composite materials and MOF materials to reduce CO2 are introduced. The method was improved, and finally focused on the core issues of improving reactivity and product selectivity, and analyzed the shortcomings of current electrocatalytic processes extended to large-scale production applications from surface engineering, chemical modification, nano or composite materials. There are other ways to improve the activity of the catalyst from these aspects, as well as the prospects for future research.},
 year = {2021}
}

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TY  - JOUR
T1  - Progress in Raman Spectroscopy and Reduction of Carbon Dioxide
AU  - Adil Emin
AU  - Tursunay Mamtimin
Y1  - 2021/11/23
PY  - 2021
N1  - https://doi.org/10.11648/j.sjc.20210906.12
DO  - 10.11648/j.sjc.20210906.12
T2  - Science Journal of Chemistry
JF  - Science Journal of Chemistry
JO  - Science Journal of Chemistry
SP  - 135
EP  - 144
PB  - Science Publishing Group
SN  - 2330-099X
UR  - https://doi.org/10.11648/j.sjc.20210906.12
AB  - The metal catalyst has good electrical conductivity, is simple to prepare and easy to be applied in practice. It is currently the most in-depth researched catalyst for electrochemical reduction of carbon dioxide. In recent decades, metals such as copper, cobalt, tin, and gold have been used as electrode catalysts for reducing carbon dioxide. From the perspective of the reduction mechanism of carbon dioxide, it is generally believed that the formation of C intermediate is the rate-determining step of the entire reduction reaction. One of the main functions of metal catalysts is to enable the corresponding reaction intermediates to exist stably, thereby improving the energy efficiency of the reaction. According to the combination with different intermediates and the different products obtained, the metal electrode catalysts can be divided into three categories. In this paper, the current research status of electrocatalytic and photocatalytic reduction of carbon dioxide and carbon dioxide under Raman spectroscopy are introduced. Also elaborate, the Raman spectroscopic characterization of carbon dioxide has been introduced in this paper with emphasis on the changes of Fermi resonance peaks of CO2 with temperature and pressure. The advantages and disadvantages of using metal and metal complexes, carbon materials, composite materials and MOF materials to reduce CO2 are introduced. The method was improved, and finally focused on the core issues of improving reactivity and product selectivity, and analyzed the shortcomings of current electrocatalytic processes extended to large-scale production applications from surface engineering, chemical modification, nano or composite materials. There are other ways to improve the activity of the catalyst from these aspects, as well as the prospects for future research.
VL  - 9
IS  - 6
ER  -

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Author Information

Adil Emin

School of Physical Science & Technology, Lanzhou University, Lanzhou, P. R. China
Tursunay Mamtimin

School of Life Sciences, Lanzhou University, Lanzhou, P. R. China

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Adil Emin, Tursunay Mamtimin. (2021). Progress in Raman Spectroscopy and Reduction of Carbon Dioxide. Science Journal of Chemistry, 9(6), 135-144. https://doi.org/10.11648/j.sjc.20210906.12

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ACS Style

Adil Emin; Tursunay Mamtimin. Progress in Raman Spectroscopy and Reduction of Carbon Dioxide. Sci. J. Chem. 2021, 9(6), 135-144. doi: 10.11648/j.sjc.20210906.12

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AMA Style

Adil Emin, Tursunay Mamtimin. Progress in Raman Spectroscopy and Reduction of Carbon Dioxide. Sci J Chem. 2021;9(6):135-144. doi: 10.11648/j.sjc.20210906.12

Copy | Download

@article{10.11648/j.sjc.20210906.12,
  author = {Adil Emin and Tursunay Mamtimin},
  title = {Progress in Raman Spectroscopy and Reduction of Carbon Dioxide},
  journal = {Science Journal of Chemistry},
  volume = {9},
  number = {6},
  pages = {135-144},
  doi = {10.11648/j.sjc.20210906.12},
  url = {https://doi.org/10.11648/j.sjc.20210906.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.sjc.20210906.12},
  abstract = {The metal catalyst has good electrical conductivity, is simple to prepare and easy to be applied in practice. It is currently the most in-depth researched catalyst for electrochemical reduction of carbon dioxide. In recent decades, metals such as copper, cobalt, tin, and gold have been used as electrode catalysts for reducing carbon dioxide. From the perspective of the reduction mechanism of carbon dioxide, it is generally believed that the formation of C intermediate is the rate-determining step of the entire reduction reaction. One of the main functions of metal catalysts is to enable the corresponding reaction intermediates to exist stably, thereby improving the energy efficiency of the reaction. According to the combination with different intermediates and the different products obtained, the metal electrode catalysts can be divided into three categories. In this paper, the current research status of electrocatalytic and photocatalytic reduction of carbon dioxide and carbon dioxide under Raman spectroscopy are introduced. Also elaborate, the Raman spectroscopic characterization of carbon dioxide has been introduced in this paper with emphasis on the changes of Fermi resonance peaks of CO2 with temperature and pressure. The advantages and disadvantages of using metal and metal complexes, carbon materials, composite materials and MOF materials to reduce CO2 are introduced. The method was improved, and finally focused on the core issues of improving reactivity and product selectivity, and analyzed the shortcomings of current electrocatalytic processes extended to large-scale production applications from surface engineering, chemical modification, nano or composite materials. There are other ways to improve the activity of the catalyst from these aspects, as well as the prospects for future research.},
 year = {2021}
}

Copy | Download

TY  - JOUR
T1  - Progress in Raman Spectroscopy and Reduction of Carbon Dioxide
AU  - Adil Emin
AU  - Tursunay Mamtimin
Y1  - 2021/11/23
PY  - 2021
N1  - https://doi.org/10.11648/j.sjc.20210906.12
DO  - 10.11648/j.sjc.20210906.12
T2  - Science Journal of Chemistry
JF  - Science Journal of Chemistry
JO  - Science Journal of Chemistry
SP  - 135
EP  - 144
PB  - Science Publishing Group
SN  - 2330-099X
UR  - https://doi.org/10.11648/j.sjc.20210906.12
AB  - The metal catalyst has good electrical conductivity, is simple to prepare and easy to be applied in practice. It is currently the most in-depth researched catalyst for electrochemical reduction of carbon dioxide. In recent decades, metals such as copper, cobalt, tin, and gold have been used as electrode catalysts for reducing carbon dioxide. From the perspective of the reduction mechanism of carbon dioxide, it is generally believed that the formation of C intermediate is the rate-determining step of the entire reduction reaction. One of the main functions of metal catalysts is to enable the corresponding reaction intermediates to exist stably, thereby improving the energy efficiency of the reaction. According to the combination with different intermediates and the different products obtained, the metal electrode catalysts can be divided into three categories. In this paper, the current research status of electrocatalytic and photocatalytic reduction of carbon dioxide and carbon dioxide under Raman spectroscopy are introduced. Also elaborate, the Raman spectroscopic characterization of carbon dioxide has been introduced in this paper with emphasis on the changes of Fermi resonance peaks of CO2 with temperature and pressure. The advantages and disadvantages of using metal and metal complexes, carbon materials, composite materials and MOF materials to reduce CO2 are introduced. The method was improved, and finally focused on the core issues of improving reactivity and product selectivity, and analyzed the shortcomings of current electrocatalytic processes extended to large-scale production applications from surface engineering, chemical modification, nano or composite materials. There are other ways to improve the activity of the catalyst from these aspects, as well as the prospects for future research.
VL  - 9
IS  - 6
ER  -

Copy | Download