Syntheses, Characterization, and X-ray Crystal Structure of Heteronuclear Zn/Na Assembled with Salen-type Schiff Base

Pokpa Haba; Mouhamadou Moustapha Sow; Mamour Sarr; Ibrahima Elhadji Thiam; Mahy Diaw; Pascal Retailleau; Mohamed Lamine Gaye

doi:doi:10.11648/j.sjc.20200805.13

Syntheses, Characterization, and X-ray Crystal Structure of Heteronuclear Zn/Na Assembled with Salen-type Schiff Base

Pokpa Haba, Mouhamadou Moustapha Sow, Mamour Sarr, Ibrahima Elhadji Thiam, Mahy Diaw, Pascal Retailleau, Mohamed Lamine Gaye

Published in Science Journal of Chemistry (Volume 8, Issue 5)

Received: 9 September 2020 Accepted: 23 September 2020 Published: 29 September 2020

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Abstract

Herein we reported the crystal structure of a dinuclear complex [{Zn^IINa^I (L)(EtOH)(NO₃)]}] (2) obtained by reaction with the metalloligand [Zn(L)].(H₂O) (1) and sodium nitrate. The metalloligand (1) and the dinuclear (2) complexes are characterized by IR and physical measurement. Spectroscopic evidence indicated that the Schiff base H₂L behave an N₂O₂O’ ₂ coordination tetradentate ligand. Suitable crystals of the compound 2 were grown by slow evaporation of ethanol solution for two weeks. The structure of 2 was elucidated by X-ray diffraction analysis. The compound crystallizes in the monoclinic crystal system with a space group of P2_1/c. The asymmetric unit of the compound contains one dideprotonated ligand molecule, on tetracoordinated zinc (II) ion, one heptacoordinated sodium(I) ion, one bidentate nitrate group and one coordinated ethanol molecule resulting in a structure formulated as [Zn(µ-L)Na(NO₃)(EtOH)]. In the structure the Zn^II ion is tetracoordinated and the environment around the zinc (II) is best described as a planar square geometry. The Na^I ion is seven-coordinated in a severely distorted bipyramid pentagon environment. The interplanar angles between the two phenyl rings with a methoxy substituent is 4.208 (4)°, while the dihedral angle values of these groups with the phenyl carrying amino groups are respectively 7.499 (5)° and 11.594 (5)°. The Zn–Na distance is 3.4244 (9) Å. In the crystal structure numerous intramolecular and intermolecular hydrogen bonds link the molecules in a three-dimensional network.

Published in	Science Journal of Chemistry (Volume 8, Issue 5)
DOI	10.11648/j.sjc.20200805.13
Page(s)	113-118
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2020. Published by Science Publishing Group

Keywords

Zinc, Metalloligand, o-vanillin, 1, 2-diaminobenzene

References

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Pokpa Haba, Mouhamadou Moustapha Sow, Mamour Sarr, Ibrahima Elhadji Thiam, Mahy Diaw, et al. (2020). Syntheses, Characterization, and X-ray Crystal Structure of Heteronuclear Zn/Na Assembled with Salen-type Schiff Base. Science Journal of Chemistry, 8(5), 113-118. https://doi.org/10.11648/j.sjc.20200805.13

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ACS Style

Pokpa Haba; Mouhamadou Moustapha Sow; Mamour Sarr; Ibrahima Elhadji Thiam; Mahy Diaw, et al. Syntheses, Characterization, and X-ray Crystal Structure of Heteronuclear Zn/Na Assembled with Salen-type Schiff Base. Sci. J. Chem. 2020, 8(5), 113-118. doi: 10.11648/j.sjc.20200805.13

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AMA Style

Pokpa Haba, Mouhamadou Moustapha Sow, Mamour Sarr, Ibrahima Elhadji Thiam, Mahy Diaw, et al. Syntheses, Characterization, and X-ray Crystal Structure of Heteronuclear Zn/Na Assembled with Salen-type Schiff Base. Sci J Chem. 2020;8(5):113-118. doi: 10.11648/j.sjc.20200805.13

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@article{10.11648/j.sjc.20200805.13,
  author = {Pokpa Haba and Mouhamadou Moustapha Sow and Mamour Sarr and Ibrahima Elhadji Thiam and Mahy Diaw and Pascal Retailleau and Mohamed Lamine Gaye},
  title = {Syntheses, Characterization, and X-ray Crystal Structure of Heteronuclear Zn/Na Assembled with Salen-type Schiff Base},
  journal = {Science Journal of Chemistry},
  volume = {8},
  number = {5},
  pages = {113-118},
  doi = {10.11648/j.sjc.20200805.13},
  url = {https://doi.org/10.11648/j.sjc.20200805.13},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.sjc.20200805.13},
  abstract = {Herein we reported the crystal structure of a dinuclear complex [{ZnIINaI (L)(EtOH)(NO3)]}] (2) obtained by reaction with the metalloligand [Zn(L)].(H2O) (1) and sodium nitrate. The metalloligand (1) and the dinuclear (2) complexes are characterized by IR and physical measurement. Spectroscopic evidence indicated that the Schiff base H2L behave an N2O2O’ 2 coordination tetradentate ligand. Suitable crystals of the compound 2 were grown by slow evaporation of ethanol solution for two weeks. The structure of 2 was elucidated by X-ray diffraction analysis. The compound crystallizes in the monoclinic crystal system with a space group of P21/c. The asymmetric unit of the compound contains one dideprotonated ligand molecule, on tetracoordinated zinc (II) ion, one heptacoordinated sodium(I) ion, one bidentate nitrate group and one coordinated ethanol molecule resulting in a structure formulated as [Zn(µ-L)Na(NO3)(EtOH)]. In the structure the ZnII ion is tetracoordinated and the environment around the zinc (II) is best described as a planar square geometry. The NaI ion is seven-coordinated in a severely distorted bipyramid pentagon environment. The interplanar angles between the two phenyl rings with a methoxy substituent is 4.208 (4)°, while the dihedral angle values of these groups with the phenyl carrying amino groups are respectively 7.499 (5)° and 11.594 (5)°. The Zn–Na distance is 3.4244 (9) Å. In the crystal structure numerous intramolecular and intermolecular hydrogen bonds link the molecules in a three-dimensional network.},
 year = {2020}
}

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TY  - JOUR
T1  - Syntheses, Characterization, and X-ray Crystal Structure of Heteronuclear Zn/Na Assembled with Salen-type Schiff Base
AU  - Pokpa Haba
AU  - Mouhamadou Moustapha Sow
AU  - Mamour Sarr
AU  - Ibrahima Elhadji Thiam
AU  - Mahy Diaw
AU  - Pascal Retailleau
AU  - Mohamed Lamine Gaye
Y1  - 2020/09/29
PY  - 2020
N1  - https://doi.org/10.11648/j.sjc.20200805.13
DO  - 10.11648/j.sjc.20200805.13
T2  - Science Journal of Chemistry
JF  - Science Journal of Chemistry
JO  - Science Journal of Chemistry
SP  - 113
EP  - 118
PB  - Science Publishing Group
SN  - 2330-099X
UR  - https://doi.org/10.11648/j.sjc.20200805.13
AB  - Herein we reported the crystal structure of a dinuclear complex [{ZnIINaI (L)(EtOH)(NO3)]}] (2) obtained by reaction with the metalloligand [Zn(L)].(H2O) (1) and sodium nitrate. The metalloligand (1) and the dinuclear (2) complexes are characterized by IR and physical measurement. Spectroscopic evidence indicated that the Schiff base H2L behave an N2O2O’ 2 coordination tetradentate ligand. Suitable crystals of the compound 2 were grown by slow evaporation of ethanol solution for two weeks. The structure of 2 was elucidated by X-ray diffraction analysis. The compound crystallizes in the monoclinic crystal system with a space group of P21/c. The asymmetric unit of the compound contains one dideprotonated ligand molecule, on tetracoordinated zinc (II) ion, one heptacoordinated sodium(I) ion, one bidentate nitrate group and one coordinated ethanol molecule resulting in a structure formulated as [Zn(µ-L)Na(NO3)(EtOH)]. In the structure the ZnII ion is tetracoordinated and the environment around the zinc (II) is best described as a planar square geometry. The NaI ion is seven-coordinated in a severely distorted bipyramid pentagon environment. The interplanar angles between the two phenyl rings with a methoxy substituent is 4.208 (4)°, while the dihedral angle values of these groups with the phenyl carrying amino groups are respectively 7.499 (5)° and 11.594 (5)°. The Zn–Na distance is 3.4244 (9) Å. In the crystal structure numerous intramolecular and intermolecular hydrogen bonds link the molecules in a three-dimensional network.
VL  - 8
IS  - 5
ER  -

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Author Information

Pokpa Haba

Department of Chemistry, University Cheikh Anta Diop, Dakar, Senegal
Mouhamadou Moustapha Sow

Department of Chemistry, University Alioune Diop, Bambey, Senegal
Mamour Sarr

Department of Chemistry, University Cheikh Anta Diop, Dakar, Senegal
Ibrahima Elhadji Thiam

Department of Chemistry, University Cheikh Anta Diop, Dakar, Senegal
Mahy Diaw

Department of Chemistry, University Alioune Diop, Bambey, Senegal
Pascal Retailleau

Natural Substances Laboratory, University Paris-Sud, Gif-sur-Yvette, France
Mohamed Lamine Gaye

Department of Chemistry, University Cheikh Anta Diop, Dakar, Senegal

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Pokpa Haba, Mouhamadou Moustapha Sow, Mamour Sarr, Ibrahima Elhadji Thiam, Mahy Diaw, et al. (2020). Syntheses, Characterization, and X-ray Crystal Structure of Heteronuclear Zn/Na Assembled with Salen-type Schiff Base. Science Journal of Chemistry, 8(5), 113-118. https://doi.org/10.11648/j.sjc.20200805.13

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ACS Style

Pokpa Haba; Mouhamadou Moustapha Sow; Mamour Sarr; Ibrahima Elhadji Thiam; Mahy Diaw, et al. Syntheses, Characterization, and X-ray Crystal Structure of Heteronuclear Zn/Na Assembled with Salen-type Schiff Base. Sci. J. Chem. 2020, 8(5), 113-118. doi: 10.11648/j.sjc.20200805.13

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AMA Style

Pokpa Haba, Mouhamadou Moustapha Sow, Mamour Sarr, Ibrahima Elhadji Thiam, Mahy Diaw, et al. Syntheses, Characterization, and X-ray Crystal Structure of Heteronuclear Zn/Na Assembled with Salen-type Schiff Base. Sci J Chem. 2020;8(5):113-118. doi: 10.11648/j.sjc.20200805.13

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@article{10.11648/j.sjc.20200805.13,
  author = {Pokpa Haba and Mouhamadou Moustapha Sow and Mamour Sarr and Ibrahima Elhadji Thiam and Mahy Diaw and Pascal Retailleau and Mohamed Lamine Gaye},
  title = {Syntheses, Characterization, and X-ray Crystal Structure of Heteronuclear Zn/Na Assembled with Salen-type Schiff Base},
  journal = {Science Journal of Chemistry},
  volume = {8},
  number = {5},
  pages = {113-118},
  doi = {10.11648/j.sjc.20200805.13},
  url = {https://doi.org/10.11648/j.sjc.20200805.13},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.sjc.20200805.13},
  abstract = {Herein we reported the crystal structure of a dinuclear complex [{ZnIINaI (L)(EtOH)(NO3)]}] (2) obtained by reaction with the metalloligand [Zn(L)].(H2O) (1) and sodium nitrate. The metalloligand (1) and the dinuclear (2) complexes are characterized by IR and physical measurement. Spectroscopic evidence indicated that the Schiff base H2L behave an N2O2O’ 2 coordination tetradentate ligand. Suitable crystals of the compound 2 were grown by slow evaporation of ethanol solution for two weeks. The structure of 2 was elucidated by X-ray diffraction analysis. The compound crystallizes in the monoclinic crystal system with a space group of P21/c. The asymmetric unit of the compound contains one dideprotonated ligand molecule, on tetracoordinated zinc (II) ion, one heptacoordinated sodium(I) ion, one bidentate nitrate group and one coordinated ethanol molecule resulting in a structure formulated as [Zn(µ-L)Na(NO3)(EtOH)]. In the structure the ZnII ion is tetracoordinated and the environment around the zinc (II) is best described as a planar square geometry. The NaI ion is seven-coordinated in a severely distorted bipyramid pentagon environment. The interplanar angles between the two phenyl rings with a methoxy substituent is 4.208 (4)°, while the dihedral angle values of these groups with the phenyl carrying amino groups are respectively 7.499 (5)° and 11.594 (5)°. The Zn–Na distance is 3.4244 (9) Å. In the crystal structure numerous intramolecular and intermolecular hydrogen bonds link the molecules in a three-dimensional network.},
 year = {2020}
}

Copy | Download

TY  - JOUR
T1  - Syntheses, Characterization, and X-ray Crystal Structure of Heteronuclear Zn/Na Assembled with Salen-type Schiff Base
AU  - Pokpa Haba
AU  - Mouhamadou Moustapha Sow
AU  - Mamour Sarr
AU  - Ibrahima Elhadji Thiam
AU  - Mahy Diaw
AU  - Pascal Retailleau
AU  - Mohamed Lamine Gaye
Y1  - 2020/09/29
PY  - 2020
N1  - https://doi.org/10.11648/j.sjc.20200805.13
DO  - 10.11648/j.sjc.20200805.13
T2  - Science Journal of Chemistry
JF  - Science Journal of Chemistry
JO  - Science Journal of Chemistry
SP  - 113
EP  - 118
PB  - Science Publishing Group
SN  - 2330-099X
UR  - https://doi.org/10.11648/j.sjc.20200805.13
AB  - Herein we reported the crystal structure of a dinuclear complex [{ZnIINaI (L)(EtOH)(NO3)]}] (2) obtained by reaction with the metalloligand [Zn(L)].(H2O) (1) and sodium nitrate. The metalloligand (1) and the dinuclear (2) complexes are characterized by IR and physical measurement. Spectroscopic evidence indicated that the Schiff base H2L behave an N2O2O’ 2 coordination tetradentate ligand. Suitable crystals of the compound 2 were grown by slow evaporation of ethanol solution for two weeks. The structure of 2 was elucidated by X-ray diffraction analysis. The compound crystallizes in the monoclinic crystal system with a space group of P21/c. The asymmetric unit of the compound contains one dideprotonated ligand molecule, on tetracoordinated zinc (II) ion, one heptacoordinated sodium(I) ion, one bidentate nitrate group and one coordinated ethanol molecule resulting in a structure formulated as [Zn(µ-L)Na(NO3)(EtOH)]. In the structure the ZnII ion is tetracoordinated and the environment around the zinc (II) is best described as a planar square geometry. The NaI ion is seven-coordinated in a severely distorted bipyramid pentagon environment. The interplanar angles between the two phenyl rings with a methoxy substituent is 4.208 (4)°, while the dihedral angle values of these groups with the phenyl carrying amino groups are respectively 7.499 (5)° and 11.594 (5)°. The Zn–Na distance is 3.4244 (9) Å. In the crystal structure numerous intramolecular and intermolecular hydrogen bonds link the molecules in a three-dimensional network.
VL  - 8
IS  - 5
ER  -

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