Preliminary Study on Blend Based Mixed Ion- Electron Conductor- (PVA: PVK): CH3COONH4: EC System

Shanker Lal Agrawal; Rajendra Prasad Kumhar

doi:doi:10.11648/j.ijmsa.20140304.12

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Preliminary Study on Blend Based Mixed Ion- Electron Conductor- (PVA: PVK): CH3COONH4: EC System

Shanker Lal Agrawal, Rajendra Prasad Kumhar

Published in International Journal of Materials Science and Applications (Volume 3, Issue 4)

Received: 5 July 2014 Accepted: 8 August 2014 Published: 20 August 2014

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Abstract

An attempt has been made in the present work to develop blend based mixed ion-electron conductor viz. PVA: PVK: CH3COONH4: EC system. Formation of polymer blend and composite has been evidenced during XRD and IR studies. Ionic conductivity of this system is seen to improve by an order of magnitude at room temperature with optimum at 1.27×10-3 S/cm for 0.4 mole ammonium acetate concentration. Ionic charge transport seems to dominate as reflected from I-t measurements. Temperature dependent conductivity shows that ionic conduction is controlled by combination of Arrhenius and VTF behavior. AC conductivity behavior is seen to be dictated by Jonscher Power law.

Published in	International Journal of Materials Science and Applications (Volume 3, Issue 4)
DOI	10.11648/j.ijmsa.20140304.12
Page(s)	129-136
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2014. Published by Science Publishing Group

Keywords

PVA: PVK Blend, CH3COONH4, PVK Based Electrolyte, Ion- Electron Conductor, Polymer Composite Electrolyte

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APA Style

Shanker Lal Agrawal, Rajendra Prasad Kumhar. (2014). Preliminary Study on Blend Based Mixed Ion- Electron Conductor- (PVA: PVK): CH3COONH4: EC System. International Journal of Materials Science and Applications, 3(4), 129-136. https://doi.org/10.11648/j.ijmsa.20140304.12

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ACS Style

Shanker Lal Agrawal; Rajendra Prasad Kumhar. Preliminary Study on Blend Based Mixed Ion- Electron Conductor- (PVA: PVK): CH3COONH4: EC System. Int. J. Mater. Sci. Appl. 2014, 3(4), 129-136. doi: 10.11648/j.ijmsa.20140304.12

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AMA Style

Shanker Lal Agrawal, Rajendra Prasad Kumhar. Preliminary Study on Blend Based Mixed Ion- Electron Conductor- (PVA: PVK): CH3COONH4: EC System. Int J Mater Sci Appl. 2014;3(4):129-136. doi: 10.11648/j.ijmsa.20140304.12

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@article{10.11648/j.ijmsa.20140304.12,
  author = {Shanker Lal Agrawal and Rajendra Prasad Kumhar},
  title = {Preliminary Study on Blend Based Mixed Ion- Electron Conductor- (PVA: PVK): CH3COONH4: EC System},
  journal = {International Journal of Materials Science and Applications},
  volume = {3},
  number = {4},
  pages = {129-136},
  doi = {10.11648/j.ijmsa.20140304.12},
  url = {https://doi.org/10.11648/j.ijmsa.20140304.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijmsa.20140304.12},
  abstract = {An attempt has been made in the present work to develop blend based mixed ion-electron conductor viz. PVA: PVK: CH3COONH4: EC system. Formation of polymer blend and composite has been evidenced during XRD and IR studies. Ionic conductivity of this system is seen to improve by an order of magnitude at room temperature with optimum at 1.27×10-3 S/cm for 0.4 mole ammonium acetate concentration. Ionic charge transport seems to dominate as reflected from I-t measurements. Temperature dependent conductivity shows that ionic conduction is controlled by combination of Arrhenius and VTF behavior. AC conductivity behavior is seen to be dictated by Jonscher Power law.},
 year = {2014}
}

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TY  - JOUR
T1  - Preliminary Study on Blend Based Mixed Ion- Electron Conductor- (PVA: PVK): CH3COONH4: EC System
AU  - Shanker Lal Agrawal
AU  - Rajendra Prasad Kumhar
Y1  - 2014/08/20
PY  - 2014
N1  - https://doi.org/10.11648/j.ijmsa.20140304.12
DO  - 10.11648/j.ijmsa.20140304.12
T2  - International Journal of Materials Science and Applications
JF  - International Journal of Materials Science and Applications
JO  - International Journal of Materials Science and Applications
SP  - 129
EP  - 136
PB  - Science Publishing Group
SN  - 2327-2643
UR  - https://doi.org/10.11648/j.ijmsa.20140304.12
AB  - An attempt has been made in the present work to develop blend based mixed ion-electron conductor viz. PVA: PVK: CH3COONH4: EC system. Formation of polymer blend and composite has been evidenced during XRD and IR studies. Ionic conductivity of this system is seen to improve by an order of magnitude at room temperature with optimum at 1.27×10-3 S/cm for 0.4 mole ammonium acetate concentration. Ionic charge transport seems to dominate as reflected from I-t measurements. Temperature dependent conductivity shows that ionic conduction is controlled by combination of Arrhenius and VTF behavior. AC conductivity behavior is seen to be dictated by Jonscher Power law.
VL  - 3
IS  - 4
ER  -

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Author Information

Shanker Lal Agrawal

SSI Laboratory Department of Physics, A P S University, Rewa India
Rajendra Prasad Kumhar

Department of Physics, Govt. Maharaja College, Chhatarpur India

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APA Style

Shanker Lal Agrawal, Rajendra Prasad Kumhar. (2014). Preliminary Study on Blend Based Mixed Ion- Electron Conductor- (PVA: PVK): CH3COONH4: EC System. International Journal of Materials Science and Applications, 3(4), 129-136. https://doi.org/10.11648/j.ijmsa.20140304.12

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ACS Style

Shanker Lal Agrawal; Rajendra Prasad Kumhar. Preliminary Study on Blend Based Mixed Ion- Electron Conductor- (PVA: PVK): CH3COONH4: EC System. Int. J. Mater. Sci. Appl. 2014, 3(4), 129-136. doi: 10.11648/j.ijmsa.20140304.12

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AMA Style

Shanker Lal Agrawal, Rajendra Prasad Kumhar. Preliminary Study on Blend Based Mixed Ion- Electron Conductor- (PVA: PVK): CH3COONH4: EC System. Int J Mater Sci Appl. 2014;3(4):129-136. doi: 10.11648/j.ijmsa.20140304.12

Copy | Download

@article{10.11648/j.ijmsa.20140304.12,
  author = {Shanker Lal Agrawal and Rajendra Prasad Kumhar},
  title = {Preliminary Study on Blend Based Mixed Ion- Electron Conductor- (PVA: PVK): CH3COONH4: EC System},
  journal = {International Journal of Materials Science and Applications},
  volume = {3},
  number = {4},
  pages = {129-136},
  doi = {10.11648/j.ijmsa.20140304.12},
  url = {https://doi.org/10.11648/j.ijmsa.20140304.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijmsa.20140304.12},
  abstract = {An attempt has been made in the present work to develop blend based mixed ion-electron conductor viz. PVA: PVK: CH3COONH4: EC system. Formation of polymer blend and composite has been evidenced during XRD and IR studies. Ionic conductivity of this system is seen to improve by an order of magnitude at room temperature with optimum at 1.27×10-3 S/cm for 0.4 mole ammonium acetate concentration. Ionic charge transport seems to dominate as reflected from I-t measurements. Temperature dependent conductivity shows that ionic conduction is controlled by combination of Arrhenius and VTF behavior. AC conductivity behavior is seen to be dictated by Jonscher Power law.},
 year = {2014}
}

Copy | Download

TY  - JOUR
T1  - Preliminary Study on Blend Based Mixed Ion- Electron Conductor- (PVA: PVK): CH3COONH4: EC System
AU  - Shanker Lal Agrawal
AU  - Rajendra Prasad Kumhar
Y1  - 2014/08/20
PY  - 2014
N1  - https://doi.org/10.11648/j.ijmsa.20140304.12
DO  - 10.11648/j.ijmsa.20140304.12
T2  - International Journal of Materials Science and Applications
JF  - International Journal of Materials Science and Applications
JO  - International Journal of Materials Science and Applications
SP  - 129
EP  - 136
PB  - Science Publishing Group
SN  - 2327-2643
UR  - https://doi.org/10.11648/j.ijmsa.20140304.12
AB  - An attempt has been made in the present work to develop blend based mixed ion-electron conductor viz. PVA: PVK: CH3COONH4: EC system. Formation of polymer blend and composite has been evidenced during XRD and IR studies. Ionic conductivity of this system is seen to improve by an order of magnitude at room temperature with optimum at 1.27×10-3 S/cm for 0.4 mole ammonium acetate concentration. Ionic charge transport seems to dominate as reflected from I-t measurements. Temperature dependent conductivity shows that ionic conduction is controlled by combination of Arrhenius and VTF behavior. AC conductivity behavior is seen to be dictated by Jonscher Power law.
VL  - 3
IS  - 4
ER  -

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