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Electrochemical Growth and Studies of Indium-Rich CuInTe2 Thin Films

Received: 8 November 2013     Published: 30 December 2013
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Abstract

CuInTe2 thin films were electrochemically deposited on fluorine-doped tin oxide (<10 Ω/□) coated glass. The electrochemical bath used for the electrodeposition of CuInTe2 thin films consisted of aqueous solution mixture of 0.025 M CuCl2, 0.1 M InCl3 and pre-reacted 0.01M tellurium with HNO3.Linear and cyclic sweep voltammograms were analysed to find out the suitable deposition potentials and growth parameters. Acetronitrile was added as a supporting electrolyte and growth was carried out at the constant deposition potentials of -350 mV and - 450 mV with and without stirring. X-ray diffraction (XRD) results obtained in this work show films that were grown under stirring conditions are more oriented in the (112) direction. CuInTe2 were also analyzed by scanning electron microscopy (SEM) and energy dispersive analysis of X-rays (EDAX). SEM study revealed the formation of uniformly covered nanoflakes of 40-50 nanometers in width and compositional analysis show that CuInTe2 film grown had an excess of indium content, but (Cu %+In%):Te% is close to stoichiometry.

Published in International Journal of Materials Science and Applications (Volume 3, Issue 1)
DOI 10.11648/j.ijmsa.20140301.11
Page(s) 1-5
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2013. Published by Science Publishing Group

Keywords

CuInTe2, Electrodeposition, XRD, SEM, Thin Films, Solar Energy Materials

References
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    Dixit Prasher, Kavita Dhakad, Ashok k. Sharma, Vikas Thakur, Poolla Rajaram. (2013). Electrochemical Growth and Studies of Indium-Rich CuInTe2 Thin Films. International Journal of Materials Science and Applications, 3(1), 1-5. https://doi.org/10.11648/j.ijmsa.20140301.11

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    ACS Style

    Dixit Prasher; Kavita Dhakad; Ashok k. Sharma; Vikas Thakur; Poolla Rajaram. Electrochemical Growth and Studies of Indium-Rich CuInTe2 Thin Films. Int. J. Mater. Sci. Appl. 2013, 3(1), 1-5. doi: 10.11648/j.ijmsa.20140301.11

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    AMA Style

    Dixit Prasher, Kavita Dhakad, Ashok k. Sharma, Vikas Thakur, Poolla Rajaram. Electrochemical Growth and Studies of Indium-Rich CuInTe2 Thin Films. Int J Mater Sci Appl. 2013;3(1):1-5. doi: 10.11648/j.ijmsa.20140301.11

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  • @article{10.11648/j.ijmsa.20140301.11,
      author = {Dixit Prasher and Kavita Dhakad and Ashok k. Sharma and Vikas Thakur and Poolla Rajaram},
      title = {Electrochemical Growth and Studies of Indium-Rich CuInTe2 Thin Films},
      journal = {International Journal of Materials Science and Applications},
      volume = {3},
      number = {1},
      pages = {1-5},
      doi = {10.11648/j.ijmsa.20140301.11},
      url = {https://doi.org/10.11648/j.ijmsa.20140301.11},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijmsa.20140301.11},
      abstract = {CuInTe2 thin films were electrochemically deposited on fluorine-doped tin oxide (<10 Ω/□) coated glass. The electrochemical bath used for the electrodeposition of CuInTe2 thin films consisted of aqueous solution mixture of 0.025 M CuCl2, 0.1 M InCl3 and pre-reacted 0.01M tellurium with HNO3.Linear and cyclic sweep voltammograms were analysed to find out the suitable deposition potentials and growth parameters. Acetronitrile was added as a supporting electrolyte and growth was carried out at the constant deposition potentials of -350 mV and - 450 mV with and without stirring. X-ray diffraction (XRD) results obtained in this work show films that were grown under stirring conditions are more oriented in the (112) direction. CuInTe2 were also analyzed by scanning electron microscopy (SEM) and energy dispersive analysis of X-rays (EDAX). SEM study revealed the formation of uniformly covered nanoflakes of 40-50 nanometers in width and compositional analysis show that CuInTe2 film grown had an excess of indium content, but (Cu %+In%):Te% is close to stoichiometry.},
     year = {2013}
    }
    

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  • TY  - JOUR
    T1  - Electrochemical Growth and Studies of Indium-Rich CuInTe2 Thin Films
    AU  - Dixit Prasher
    AU  - Kavita Dhakad
    AU  - Ashok k. Sharma
    AU  - Vikas Thakur
    AU  - Poolla Rajaram
    Y1  - 2013/12/30
    PY  - 2013
    N1  - https://doi.org/10.11648/j.ijmsa.20140301.11
    DO  - 10.11648/j.ijmsa.20140301.11
    T2  - International Journal of Materials Science and Applications
    JF  - International Journal of Materials Science and Applications
    JO  - International Journal of Materials Science and Applications
    SP  - 1
    EP  - 5
    PB  - Science Publishing Group
    SN  - 2327-2643
    UR  - https://doi.org/10.11648/j.ijmsa.20140301.11
    AB  - CuInTe2 thin films were electrochemically deposited on fluorine-doped tin oxide (<10 Ω/□) coated glass. The electrochemical bath used for the electrodeposition of CuInTe2 thin films consisted of aqueous solution mixture of 0.025 M CuCl2, 0.1 M InCl3 and pre-reacted 0.01M tellurium with HNO3.Linear and cyclic sweep voltammograms were analysed to find out the suitable deposition potentials and growth parameters. Acetronitrile was added as a supporting electrolyte and growth was carried out at the constant deposition potentials of -350 mV and - 450 mV with and without stirring. X-ray diffraction (XRD) results obtained in this work show films that were grown under stirring conditions are more oriented in the (112) direction. CuInTe2 were also analyzed by scanning electron microscopy (SEM) and energy dispersive analysis of X-rays (EDAX). SEM study revealed the formation of uniformly covered nanoflakes of 40-50 nanometers in width and compositional analysis show that CuInTe2 film grown had an excess of indium content, but (Cu %+In%):Te% is close to stoichiometry.
    VL  - 3
    IS  - 1
    ER  - 

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Author Information
  • School of Studies in Physics, Jiwaji University, Gwalior 474011- India

  • School of Studies in Physics, Jiwaji University, Gwalior 474011- India

  • School of Studies in Physics, Jiwaji University, Gwalior 474011- India

  • School of Studies in Physics, Jiwaji University, Gwalior 474011- India

  • School of Studies in Physics, Jiwaji University, Gwalior 474011- India

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