Synthesis and Structural Studies of Nickel Complex Supported by-ONNO-Tetra Dentate Schiff-Base Ligand: Efficient Catalysts for Oxidation of Phenol

Alekha Kumar Sutar; Yasobanta Das; Sasmita Pattnaik; Nibedita Nath; Prasanta Rath; Tungabidya Maharana

doi:doi:10.11648/j.ijmsa.20130204.13

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Synthesis and Structural Studies of Nickel Complex Supported by-ONNO-Tetra Dentate Schiff-Base Ligand: Efficient Catalysts for Oxidation of Phenol

Alekha Kumar Sutar, Yasobanta Das, Sasmita Pattnaik, Nibedita Nath, Prasanta Rath, Tungabidya Maharana

Published in International Journal of Materials Science and Applications (Volume 2, Issue 4)

Received: 2 July 2013 Published: 10 August 2013

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Abstract

The free and polymer anchored complex of nickel [3-MHBdMBn-Ni and P-3-MHBdMBn-Ni], supported by -ONNO-tetradentate Schiff-base ligand are prepared by the reactions of nickel solution with one molar equivalent of unsupported 3-MHBdMBn (N, N'-bis (2-hydroxy-3-methylbenzaldehyde) 4-Methylbenzene-1,2-diamine) or polymer supported (P-3-MHBdMBn) Schiff-base ligands in methanol. The structural study reveal that nickel (II) complex of 3-MHBdMBn Schiff base is square planar in geometry. Complexation of nickel ion increased the thermal stability of 3-MHBdMBn Schiff base. The catalytic activity of nickel complex towards the oxidation of phenol is investigated in the presence of hydrogen peroxide. Experimental results indicate that the reactivity of P-3-MHBdMBn-Ni is dramatically affected by the polymer support over 3-MHBdMBn-Ni and the rate of oxidation (Rp) for unsupported one is 1.28 x 10-6 mole dm-3 s-1 and for supported analogue is 1.99 x 10-6 mole dm-3 s-1.

Published in	International Journal of Materials Science and Applications (Volume 2, Issue 4)
DOI	10.11648/j.ijmsa.20130204.13
Page(s)	136-145
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2013. Published by Science Publishing Group

Keywords

Schiff Base, Polymer Support, Catalysis, Nickel, Phenol, Oxidation

References

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APA Style

Alekha Kumar Sutar, Yasobanta Das, Sasmita Pattnaik, Nibedita Nath, Prasanta Rath, et al. (2013). Synthesis and Structural Studies of Nickel Complex Supported by-ONNO-Tetra Dentate Schiff-Base Ligand: Efficient Catalysts for Oxidation of Phenol. International Journal of Materials Science and Applications, 2(4), 136-145. https://doi.org/10.11648/j.ijmsa.20130204.13

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ACS Style

Alekha Kumar Sutar; Yasobanta Das; Sasmita Pattnaik; Nibedita Nath; Prasanta Rath, et al. Synthesis and Structural Studies of Nickel Complex Supported by-ONNO-Tetra Dentate Schiff-Base Ligand: Efficient Catalysts for Oxidation of Phenol. Int. J. Mater. Sci. Appl. 2013, 2(4), 136-145. doi: 10.11648/j.ijmsa.20130204.13

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AMA Style

Alekha Kumar Sutar, Yasobanta Das, Sasmita Pattnaik, Nibedita Nath, Prasanta Rath, et al. Synthesis and Structural Studies of Nickel Complex Supported by-ONNO-Tetra Dentate Schiff-Base Ligand: Efficient Catalysts for Oxidation of Phenol. Int J Mater Sci Appl. 2013;2(4):136-145. doi: 10.11648/j.ijmsa.20130204.13

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@article{10.11648/j.ijmsa.20130204.13,
  author = {Alekha Kumar Sutar and Yasobanta Das and Sasmita Pattnaik and Nibedita Nath and Prasanta Rath and Tungabidya Maharana},
  title = {Synthesis and Structural Studies of Nickel Complex Supported by-ONNO-Tetra Dentate Schiff-Base Ligand: Efficient Catalysts for Oxidation of Phenol},
  journal = {International Journal of Materials Science and Applications},
  volume = {2},
  number = {4},
  pages = {136-145},
  doi = {10.11648/j.ijmsa.20130204.13},
  url = {https://doi.org/10.11648/j.ijmsa.20130204.13},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijmsa.20130204.13},
  abstract = {The free and polymer anchored complex of nickel [3-MHBdMBn-Ni and P-3-MHBdMBn-Ni], supported by -ONNO-tetradentate Schiff-base ligand are prepared by the reactions of nickel solution with one molar equivalent of unsupported 3-MHBdMBn (N, N'-bis (2-hydroxy-3-methylbenzaldehyde) 4-Methylbenzene-1,2-diamine) or polymer supported (P-3-MHBdMBn) Schiff-base ligands in methanol. The structural study reveal that nickel (II) complex of 3-MHBdMBn Schiff base is square planar in geometry. Complexation of nickel ion increased the thermal stability of 3-MHBdMBn Schiff base. The catalytic activity of nickel complex towards the oxidation of phenol is investigated in the presence of hydrogen peroxide. Experimental results indicate that the reactivity of P-3-MHBdMBn-Ni is dramatically affected by the polymer support over 3-MHBdMBn-Ni and the rate of oxidation (Rp) for unsupported one is 1.28 x 10-6 mole dm-3 s-1 and for supported analogue is 1.99 x 10-6 mole dm-3 s-1.},
 year = {2013}
}

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TY  - JOUR
T1  - Synthesis and Structural Studies of Nickel Complex Supported by-ONNO-Tetra Dentate Schiff-Base Ligand: Efficient Catalysts for Oxidation of Phenol
AU  - Alekha Kumar Sutar
AU  - Yasobanta Das
AU  - Sasmita Pattnaik
AU  - Nibedita Nath
AU  - Prasanta Rath
AU  - Tungabidya Maharana
Y1  - 2013/08/10
PY  - 2013
N1  - https://doi.org/10.11648/j.ijmsa.20130204.13
DO  - 10.11648/j.ijmsa.20130204.13
T2  - International Journal of Materials Science and Applications
JF  - International Journal of Materials Science and Applications
JO  - International Journal of Materials Science and Applications
SP  - 136
EP  - 145
PB  - Science Publishing Group
SN  - 2327-2643
UR  - https://doi.org/10.11648/j.ijmsa.20130204.13
AB  - The free and polymer anchored complex of nickel [3-MHBdMBn-Ni and P-3-MHBdMBn-Ni], supported by -ONNO-tetradentate Schiff-base ligand are prepared by the reactions of nickel solution with one molar equivalent of unsupported 3-MHBdMBn (N, N'-bis (2-hydroxy-3-methylbenzaldehyde) 4-Methylbenzene-1,2-diamine) or polymer supported (P-3-MHBdMBn) Schiff-base ligands in methanol. The structural study reveal that nickel (II) complex of 3-MHBdMBn Schiff base is square planar in geometry. Complexation of nickel ion increased the thermal stability of 3-MHBdMBn Schiff base. The catalytic activity of nickel complex towards the oxidation of phenol is investigated in the presence of hydrogen peroxide. Experimental results indicate that the reactivity of P-3-MHBdMBn-Ni is dramatically affected by the polymer support over 3-MHBdMBn-Ni and the rate of oxidation (Rp) for unsupported one is 1.28 x 10-6 mole dm-3 s-1 and for supported analogue is 1.99 x 10-6 mole dm-3 s-1.
VL  - 2
IS  - 4
ER  -

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Author Information

Alekha Kumar Sutar

Catalysis Research Lab, Department of Chemistry, Ravenshaw University, Cuttack-3, Odisha, India
Yasobanta Das

School of Applied Sciences (Chemistry), KIIT University, Bhubaneswar, Odisha, India
Sasmita Pattnaik

Catalysis Research Lab, Department of Chemistry, Ravenshaw University, Cuttack-3, Odisha, India
Nibedita Nath

Catalysis Research Lab, Department of Chemistry, Ravenshaw University, Cuttack-3, Odisha, India
Prasanta Rath

School of Applied Sciences (Chemistry), KIIT University, Bhubaneswar, Odisha, India
Tungabidya Maharana

Department of Chemistry, National Institute of Technology, Raipur, India

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APA Style

Alekha Kumar Sutar, Yasobanta Das, Sasmita Pattnaik, Nibedita Nath, Prasanta Rath, et al. (2013). Synthesis and Structural Studies of Nickel Complex Supported by-ONNO-Tetra Dentate Schiff-Base Ligand: Efficient Catalysts for Oxidation of Phenol. International Journal of Materials Science and Applications, 2(4), 136-145. https://doi.org/10.11648/j.ijmsa.20130204.13

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ACS Style

Alekha Kumar Sutar; Yasobanta Das; Sasmita Pattnaik; Nibedita Nath; Prasanta Rath, et al. Synthesis and Structural Studies of Nickel Complex Supported by-ONNO-Tetra Dentate Schiff-Base Ligand: Efficient Catalysts for Oxidation of Phenol. Int. J. Mater. Sci. Appl. 2013, 2(4), 136-145. doi: 10.11648/j.ijmsa.20130204.13

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AMA Style

Alekha Kumar Sutar, Yasobanta Das, Sasmita Pattnaik, Nibedita Nath, Prasanta Rath, et al. Synthesis and Structural Studies of Nickel Complex Supported by-ONNO-Tetra Dentate Schiff-Base Ligand: Efficient Catalysts for Oxidation of Phenol. Int J Mater Sci Appl. 2013;2(4):136-145. doi: 10.11648/j.ijmsa.20130204.13

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@article{10.11648/j.ijmsa.20130204.13,
  author = {Alekha Kumar Sutar and Yasobanta Das and Sasmita Pattnaik and Nibedita Nath and Prasanta Rath and Tungabidya Maharana},
  title = {Synthesis and Structural Studies of Nickel Complex Supported by-ONNO-Tetra Dentate Schiff-Base Ligand: Efficient Catalysts for Oxidation of Phenol},
  journal = {International Journal of Materials Science and Applications},
  volume = {2},
  number = {4},
  pages = {136-145},
  doi = {10.11648/j.ijmsa.20130204.13},
  url = {https://doi.org/10.11648/j.ijmsa.20130204.13},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijmsa.20130204.13},
  abstract = {The free and polymer anchored complex of nickel [3-MHBdMBn-Ni and P-3-MHBdMBn-Ni], supported by -ONNO-tetradentate Schiff-base ligand are prepared by the reactions of nickel solution with one molar equivalent of unsupported 3-MHBdMBn (N, N'-bis (2-hydroxy-3-methylbenzaldehyde) 4-Methylbenzene-1,2-diamine) or polymer supported (P-3-MHBdMBn) Schiff-base ligands in methanol. The structural study reveal that nickel (II) complex of 3-MHBdMBn Schiff base is square planar in geometry. Complexation of nickel ion increased the thermal stability of 3-MHBdMBn Schiff base. The catalytic activity of nickel complex towards the oxidation of phenol is investigated in the presence of hydrogen peroxide. Experimental results indicate that the reactivity of P-3-MHBdMBn-Ni is dramatically affected by the polymer support over 3-MHBdMBn-Ni and the rate of oxidation (Rp) for unsupported one is 1.28 x 10-6 mole dm-3 s-1 and for supported analogue is 1.99 x 10-6 mole dm-3 s-1.},
 year = {2013}
}

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TY  - JOUR
T1  - Synthesis and Structural Studies of Nickel Complex Supported by-ONNO-Tetra Dentate Schiff-Base Ligand: Efficient Catalysts for Oxidation of Phenol
AU  - Alekha Kumar Sutar
AU  - Yasobanta Das
AU  - Sasmita Pattnaik
AU  - Nibedita Nath
AU  - Prasanta Rath
AU  - Tungabidya Maharana
Y1  - 2013/08/10
PY  - 2013
N1  - https://doi.org/10.11648/j.ijmsa.20130204.13
DO  - 10.11648/j.ijmsa.20130204.13
T2  - International Journal of Materials Science and Applications
JF  - International Journal of Materials Science and Applications
JO  - International Journal of Materials Science and Applications
SP  - 136
EP  - 145
PB  - Science Publishing Group
SN  - 2327-2643
UR  - https://doi.org/10.11648/j.ijmsa.20130204.13
AB  - The free and polymer anchored complex of nickel [3-MHBdMBn-Ni and P-3-MHBdMBn-Ni], supported by -ONNO-tetradentate Schiff-base ligand are prepared by the reactions of nickel solution with one molar equivalent of unsupported 3-MHBdMBn (N, N'-bis (2-hydroxy-3-methylbenzaldehyde) 4-Methylbenzene-1,2-diamine) or polymer supported (P-3-MHBdMBn) Schiff-base ligands in methanol. The structural study reveal that nickel (II) complex of 3-MHBdMBn Schiff base is square planar in geometry. Complexation of nickel ion increased the thermal stability of 3-MHBdMBn Schiff base. The catalytic activity of nickel complex towards the oxidation of phenol is investigated in the presence of hydrogen peroxide. Experimental results indicate that the reactivity of P-3-MHBdMBn-Ni is dramatically affected by the polymer support over 3-MHBdMBn-Ni and the rate of oxidation (Rp) for unsupported one is 1.28 x 10-6 mole dm-3 s-1 and for supported analogue is 1.99 x 10-6 mole dm-3 s-1.
VL  - 2
IS  - 4
ER  -

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