Refractive Indices for the Binary Mixtures of <i>N,N</i>-Dimethylformamide with 2-Butanol and 2-Pentanol at Temperatures 303.15 K, 313.15 K, and 323.15 K

Aklima Jahan; Md. Ashraful Alam; Md. Ashiqur Rahman Khan; Shamim Akhtar

doi:doi:10.11648/j.ajpc.20180704.11

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Refractive Indices for the Binary Mixtures of N,N-Dimethylformamide with 2-Butanol and 2-Pentanol at Temperatures 303.15 K, 313.15 K, and 323.15 K

Aklima Jahan, Md. Ashraful Alam, Md. Ashiqur Rahman Khan, Shamim Akhtar

Published in American Journal of Physical Chemistry (Volume 7, Issue 4)

Received: 8 December 2018 Accepted: 20 December 2018 Published: 10 January 2019

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Abstract

The refractive index values have been measured as a function of composition range at temperatures 303.15 K, 313.15 K, and 323.15 K and at ambient pressure and reported here. From these data, refractive index deviations, Δn_D, excess molar refraction, R_m^E, were calculated and correlated by the Redlich-Kister-type polynomial equation to derive the coefficients and estimated the standard deviation values. For both systems, ΔnD were found to be both positive and negative. Excess molar refraction, R_m^E, versus mole fraction, x1, of N,N-dimethylformamide curves were calculated and found as sigmoid at all temperatures. The variation of these properties with composition and temperature of the binary mixtures were discussed in terms of intermolecular interactions.

Published in	American Journal of Physical Chemistry (Volume 7, Issue 4)
DOI	10.11648/j.ajpc.20180704.11
Page(s)	55-62
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2019. Published by Science Publishing Group

Keywords

N,N-Dimethylformamide, 2-Butanol, 2-Pentanol, Refractive Index Deviations, Molecular Interactions

References

[1]	Rogers, R. D., Seddon, K. N. (2005): Ionic Liquids IIIA: Fundamentals, Progress, Challenges and Opportunities, American Chemical Society, Washington.
[2]	Farid, I., Dossoki, E. l. (2007): Refractive Index and Density Measurements for Selected Binary Protic-Protic, Aprotic-Aprotic, and Aprotic-Protic Systems at Temperatures from 298.15 K to 308.15 K. Journal of Chinese Chemical Society. 54, 1129-1137.
[3]	Gascom, I., Artigas, H., Lafunte, C., Lopez, M. C. (2002): Excess properties of the ternary system cyclohexane + 1,3-dioxolane + 1-butanol at 298.15 and 313.15 K, Fluid Phase Equilibr. 202, 385-397.
[4]	Gupta, M. M., Vibhu, I., Shukla, J. P. (2010): Refractive index, molar refraction deviation and excess molar volume of binary mixtures of 1,4-dioxane with carboxylic acids, Physics and Chemistry of Liquids. 48, 415–427.
[5]	Shuqin, L., Xingen, H., Ruisen, L. (1999): Apparent Molar Volumes of Sodium Chlorobenzoates in N,N-dimethylformamide−Water Mixtures at 298.15 K. J. Chem. Eng. Data. 44, 353-356.
[6]	Krestov, G. A. (1991): Thermodynamics of Solvation; Eills Harwood: England.
[7]	Marcus, Y. (1977): Introduction to Liquid-State Chemistry, Wiley-Inter-science: London.
[8]	Venkatesu, P. (2010): Thermophysical contribution of N, N-dimethylformamide in the molecular interactions with other solvents. Fluid Phase Equilib. 298, 173–191.
[9]	Krishna, T. V., Mohan, T. M. (2012): Study of molecular interactions in the polar binary mixtures of N-methyl aniline and alcohols, using excess dielectric and thermodynamic parameters. J. Chem. Thermodyn. 47, 267–275.
[10]	Singh, S., Parveen, S., Shukla, D., Gupta, M., Shukla, J. P. (2007): Volumetric, Optical, Acoustical and Viscometric Study of Molecular Association in Binary Mixtures of Butylamine with 1-Butanol and Tert-Butanol. Acta Phys. Pol. 68, 847–858.
[11]	Bai, T. C., Yao, J., Han, S. J. (1998): Excess molar volumes for ternary mixture N, N-dimethylformamide + 1-propanol + water at the temperature 298.15 K. Fluid Phase Equilib. 152, 283–298.
[12]	Serbanovic, S. P., Kijevcanin, M. L., Radovic, I. R., Djordjevic, B. (2006): Effect of temperature on the excess molar volumes of some alcohol + aromatic mixtures and modelling by cubic EOS mixing rules. Fluid Phase Equilib. 239, 69–82.
[13]	Bhatia, S. C., Tripathi, N., Dubey, G. P. (2002): Refractive indices of binary liquid mixtures of (decane + benzene) and (hexadecane + benzene, or + hexane) at 303.15, 308.15 and 313.15K, Ind. J. Chem. 41, 266-269.
[14]	Sharma, S., Patel, P. B., Patel, R. S., Vora, J. J. E.: (2007): J. Chem. 4, 343-349.
[15]	Mehra, R. (2003): Proc. Indian Acad. Sci. 115, 147-1547.
[16]	Fermeglia, M., Torriano, G. (1999): Density, Viscosity, and Refractive Index for Binary Systems of n-C16 and Four Nonlinear Alkanes at 298.15 K. J. Chem. Eng. Data. 44, 965-969.
[17]	Naya, K. J. N., Aralaguppi, M. I., Toti, U. S., Bhavi, T. M. A. (2003): Density, Viscosity, Refractive Index, and Speed of Sound in the Binary Mixtures of Tri-n-butylamine + Triethylamine, + Tetrahydrofuran, + Tetradecane, + Tetrachloroethylene, + Pyridine, or + Trichloroethylene at (298.15, 303.15, and 308.15) K. J. Chem. Eng. Data. 48, 1483-1488.
[18]	Pandey, J. D., Shukla, R. K., Rai, R. D., Shukla, A. K. (1992): Indian J. Pure & Appl. Phys. 30, 94-97.
[19]	International Union of Pure and Applied Chemistry. (1986): Inorganic Chemistry Division, Commission on Atomic Weights and Isotropic Abundances. Pure appl. Chem. 58, 1677-1692.
[20]	Jorgensen, S. E., Sorensen, B. H., Mahler, H. (1998): Handbook of estimation methods in ecotoxicology and environmental chemistry. Washington (DC): Lewis Publishers, p. 14.
[21]	Leron, R. B., Soriano, N., Li, M. H. (2012): Densities and refractive indices of the deep eutectic solvents (choline chloride + ethylene glycol or glycerol) and their aqueous mixtures at the temperature ranging from 298.15 to 333.15 K. J Taiwan Inst Chem Eng. 43, 551–557.
[22]	Rilo, E., Domínguez-Pérez, M., Vila, J. et al. (2012): Easy prediction of the refractive index for binary mixtures of ionic liquids with water or ethanol. J Chem Thermodyn. 47, 219–222.
[23]	Kier, L. B., Hall, L. H. (1976): Molecular connectivity in chemistry and drug research. Sand Diego (CA): Academic Press.
[24]	Rechsteiner, C. E. Lyman, W. J., Reehl, W. F., Rosenblatt, D. H. (1990): Hand book of chemical property estimation. Washington (DC): American Chemical Society. 12, 8-16.
[25]	Ali, A., Nain, A. K., Lal, B., Chand, D. (2004): Densities, Viscosities, and Refractive Indices of Binary Mixtures of Benzene with Isomeric Butanols at 30°C. International Journal of Thermophysics. 25, 1835-1847.
[26]	Baragi, J. G., Aralaguppi, M. I., Aminabhavi, T. M., Kariduraganavar, M. Y., Kittur, A. S. (2005): Density, Viscosity, Refractive Index, and Speed of Sound for Binary Mixtures of Anisole with 2- Chloroethanol, 1,4-Dioxane, Tetrachloroethylene, Tetrachloroethane, DMF, DMSO, and Diethyl Oxalate at (298.15, 303.15, and 308.15) K. J. Chem. Eng. Data. 50, 910-916.
[27]	Redlich, O., Kister, A. T. (1948): Algebraic Representation of Thermodynamic Properties and the Classification of Solutions. Ind. Eng. Chem. 44, 345–348.

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Aklima Jahan, Md. Ashraful Alam, Md. Ashiqur Rahman Khan, Shamim Akhtar. (2019). Refractive Indices for the Binary Mixtures of N,N-Dimethylformamide with 2-Butanol and 2-Pentanol at Temperatures 303.15 K, 313.15 K, and 323.15 K. American Journal of Physical Chemistry, 7(4), 55-62. https://doi.org/10.11648/j.ajpc.20180704.11

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Aklima Jahan; Md. Ashraful Alam; Md. Ashiqur Rahman Khan; Shamim Akhtar. Refractive Indices for the Binary Mixtures of N,N-Dimethylformamide with 2-Butanol and 2-Pentanol at Temperatures 303.15 K, 313.15 K, and 323.15 K. Am. J. Phys. Chem. 2019, 7(4), 55-62. doi: 10.11648/j.ajpc.20180704.11

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AMA Style

Aklima Jahan, Md. Ashraful Alam, Md. Ashiqur Rahman Khan, Shamim Akhtar. Refractive Indices for the Binary Mixtures of N,N-Dimethylformamide with 2-Butanol and 2-Pentanol at Temperatures 303.15 K, 313.15 K, and 323.15 K. Am J Phys Chem. 2019;7(4):55-62. doi: 10.11648/j.ajpc.20180704.11

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@article{10.11648/j.ajpc.20180704.11,
  author = {Aklima Jahan and Md. Ashraful Alam and Md. Ashiqur Rahman Khan and Shamim Akhtar},
  title = {Refractive Indices for the Binary Mixtures of N,N-Dimethylformamide with 2-Butanol and 2-Pentanol at Temperatures 303.15 K, 313.15 K, and 323.15 K},
  journal = {American Journal of Physical Chemistry},
  volume = {7},
  number = {4},
  pages = {55-62},
  doi = {10.11648/j.ajpc.20180704.11},
  url = {https://doi.org/10.11648/j.ajpc.20180704.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajpc.20180704.11},
  abstract = {The refractive index values have been measured as a function of composition range at temperatures 303.15 K, 313.15 K, and 323.15 K and at ambient pressure and reported here. From these data, refractive index deviations, ΔnD, excess molar refraction, RmE, were calculated and correlated by the Redlich-Kister-type polynomial equation to derive the coefficients and estimated the standard deviation values. For both systems, ΔnD were found to be both positive and negative. Excess molar refraction, RmE, versus mole fraction, x1, of N,N-dimethylformamide curves were calculated and found as sigmoid at all temperatures. The variation of these properties with composition and temperature of the binary mixtures were discussed in terms of intermolecular interactions.},
 year = {2019}
}

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TY  - JOUR
T1  - Refractive Indices for the Binary Mixtures of N,N-Dimethylformamide with 2-Butanol and 2-Pentanol at Temperatures 303.15 K, 313.15 K, and 323.15 K
AU  - Aklima Jahan
AU  - Md. Ashraful Alam
AU  - Md. Ashiqur Rahman Khan
AU  - Shamim Akhtar
Y1  - 2019/01/10
PY  - 2019
N1  - https://doi.org/10.11648/j.ajpc.20180704.11
DO  - 10.11648/j.ajpc.20180704.11
T2  - American Journal of Physical Chemistry
JF  - American Journal of Physical Chemistry
JO  - American Journal of Physical Chemistry
SP  - 55
EP  - 62
PB  - Science Publishing Group
SN  - 2327-2449
UR  - https://doi.org/10.11648/j.ajpc.20180704.11
AB  - The refractive index values have been measured as a function of composition range at temperatures 303.15 K, 313.15 K, and 323.15 K and at ambient pressure and reported here. From these data, refractive index deviations, ΔnD, excess molar refraction, RmE, were calculated and correlated by the Redlich-Kister-type polynomial equation to derive the coefficients and estimated the standard deviation values. For both systems, ΔnD were found to be both positive and negative. Excess molar refraction, RmE, versus mole fraction, x1, of N,N-dimethylformamide curves were calculated and found as sigmoid at all temperatures. The variation of these properties with composition and temperature of the binary mixtures were discussed in terms of intermolecular interactions.
VL  - 7
IS  - 4
ER  -

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Author Information

Aklima Jahan

Department of Chemistry, University of Chittagong, Chittagong, Bangladesh
Md. Ashraful Alam

Department of Chemistry and Bioengineering, Iwate University, Morioka, Japan
Md. Ashiqur Rahman Khan

Department of Chemistry, University of Chittagong, Chittagong, Bangladesh
Shamim Akhtar

Department of Chemistry, University of Chittagong, Chittagong, Bangladesh

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APA Style

Aklima Jahan, Md. Ashraful Alam, Md. Ashiqur Rahman Khan, Shamim Akhtar. (2019). Refractive Indices for the Binary Mixtures of N,N-Dimethylformamide with 2-Butanol and 2-Pentanol at Temperatures 303.15 K, 313.15 K, and 323.15 K. American Journal of Physical Chemistry, 7(4), 55-62. https://doi.org/10.11648/j.ajpc.20180704.11

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ACS Style

Aklima Jahan; Md. Ashraful Alam; Md. Ashiqur Rahman Khan; Shamim Akhtar. Refractive Indices for the Binary Mixtures of N,N-Dimethylformamide with 2-Butanol and 2-Pentanol at Temperatures 303.15 K, 313.15 K, and 323.15 K. Am. J. Phys. Chem. 2019, 7(4), 55-62. doi: 10.11648/j.ajpc.20180704.11

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AMA Style

Aklima Jahan, Md. Ashraful Alam, Md. Ashiqur Rahman Khan, Shamim Akhtar. Refractive Indices for the Binary Mixtures of N,N-Dimethylformamide with 2-Butanol and 2-Pentanol at Temperatures 303.15 K, 313.15 K, and 323.15 K. Am J Phys Chem. 2019;7(4):55-62. doi: 10.11648/j.ajpc.20180704.11

Copy | Download

@article{10.11648/j.ajpc.20180704.11,
  author = {Aklima Jahan and Md. Ashraful Alam and Md. Ashiqur Rahman Khan and Shamim Akhtar},
  title = {Refractive Indices for the Binary Mixtures of N,N-Dimethylformamide with 2-Butanol and 2-Pentanol at Temperatures 303.15 K, 313.15 K, and 323.15 K},
  journal = {American Journal of Physical Chemistry},
  volume = {7},
  number = {4},
  pages = {55-62},
  doi = {10.11648/j.ajpc.20180704.11},
  url = {https://doi.org/10.11648/j.ajpc.20180704.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajpc.20180704.11},
  abstract = {The refractive index values have been measured as a function of composition range at temperatures 303.15 K, 313.15 K, and 323.15 K and at ambient pressure and reported here. From these data, refractive index deviations, ΔnD, excess molar refraction, RmE, were calculated and correlated by the Redlich-Kister-type polynomial equation to derive the coefficients and estimated the standard deviation values. For both systems, ΔnD were found to be both positive and negative. Excess molar refraction, RmE, versus mole fraction, x1, of N,N-dimethylformamide curves were calculated and found as sigmoid at all temperatures. The variation of these properties with composition and temperature of the binary mixtures were discussed in terms of intermolecular interactions.},
 year = {2019}
}

Copy | Download

TY  - JOUR
T1  - Refractive Indices for the Binary Mixtures of N,N-Dimethylformamide with 2-Butanol and 2-Pentanol at Temperatures 303.15 K, 313.15 K, and 323.15 K
AU  - Aklima Jahan
AU  - Md. Ashraful Alam
AU  - Md. Ashiqur Rahman Khan
AU  - Shamim Akhtar
Y1  - 2019/01/10
PY  - 2019
N1  - https://doi.org/10.11648/j.ajpc.20180704.11
DO  - 10.11648/j.ajpc.20180704.11
T2  - American Journal of Physical Chemistry
JF  - American Journal of Physical Chemistry
JO  - American Journal of Physical Chemistry
SP  - 55
EP  - 62
PB  - Science Publishing Group
SN  - 2327-2449
UR  - https://doi.org/10.11648/j.ajpc.20180704.11
AB  - The refractive index values have been measured as a function of composition range at temperatures 303.15 K, 313.15 K, and 323.15 K and at ambient pressure and reported here. From these data, refractive index deviations, ΔnD, excess molar refraction, RmE, were calculated and correlated by the Redlich-Kister-type polynomial equation to derive the coefficients and estimated the standard deviation values. For both systems, ΔnD were found to be both positive and negative. Excess molar refraction, RmE, versus mole fraction, x1, of N,N-dimethylformamide curves were calculated and found as sigmoid at all temperatures. The variation of these properties with composition and temperature of the binary mixtures were discussed in terms of intermolecular interactions.
VL  - 7
IS  - 4
ER  -

Copy | Download