| Peer-Reviewed

Polyelektrolite Solutions and Molecular Descriptions of Biopolymer Macroions

Received: 18 August 2022     Accepted: 14 September 2022     Published: 10 January 2023
Views:       Downloads:
Abstract

Molecular mass characteristics of samples of ionic biopolymers, including chitosan and fibroin, the manifestation of physical conditions depending on the concentration of macroions, and hydrodynamic, rheological methods were used in the implementation of these studies. These processes depend on the fact that ionic polymers exhibit viscosity in relation to their molecular mass and are sensitive to the effects of the electric field at the expense of ionogenic groups. In order to determine this, the results of studies on the molecular characteristics of basic polymer objects were discussed. When polyelectrolytes are affected by external forces, including mechanical or electrical stresses, gradient fields are created, and macroions move along the lines of force of these fields. Such fields are observed, for example, when a liquid flows from a capillary under mechanical pressure, when the liquid is turned into a stable laminar flow using a rotor, or when ions and macroions move towards the poles (electrodes) during electrophoresis and electrolysis. In general, in the gradient field created under the influence of mechanical influence, the macroions move along the lines of force in rotation and advance, while in the gradient field created under the influence of electric voltage, the functional groups of macroions move towards the anode or cathode as anions or cations. The reason for the choice of poles is the sensitivity of anions or cations to the effect of an electric field.

Published in American Journal of Modern Physics (Volume 11, Issue 6)
DOI 10.11648/j.ajmp.20221106.11
Page(s) 92-94
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2023. Published by Science Publishing Group

Keywords

Macroion, Fibroin, Chitosan, Viscosity, Solution, Macromolecules

References
[1] S. Hina, Y. Zhang and H. Wang. Rev. Adv. Mater Sci. 36 (2014) 165-176 p.
[2] Picout DR, Ross-Murphy SB. Rheology of biopolymer solutions and gels. Scientific World Journal. 2003 Mar 24; 3: 105-21. doi: 10.1100/tsw.2003.15. PMID: 12806124; PMCID: PMC5974903.
[3] Marucho M. A Java Application to Characterize Biomolecules and Nanomaterials in Electrolyte Aqueous Solutions. Comput Phys Commun. 2019 Sep; 242: 104-119. doi: 10.1016/j.cpc.2019.03.022. Epub 2019 Apr 30. PMID: 31827306; PMCID: PMC6905646.
[4] Hamman JH. Chitosan based polyelectrolyte complexes as potential carrier materials in drug delivery systems. Mar Drugs. 2010 Apr 19; 8 (4): 1305-22. doi: 10.3390/md8041305. PMID: 20479980; PMCID: PMC2866488.
[5] Singh R, Shitiz K, Singh A. Chitin and chitosan: biopolymers for wound management. Int Wound J. 2017 Dec; 14 (6): 1276-1289. doi: 10.1111/iwj.12797. Epub 2017 Aug 10. PMID: 28799228; PMCID: PMC7949833.
[6] Khakkulov J. M. Chitosan and fibroin polyelectrolyte solutions and molecular characteristics. Republican Scientific Conference “Modern Problems of Polymer Science” 25-26 November 2020 p. 88-90.
[7] Martin A. Masuelli. Intrinsic Viscosity Determination of High Molecular Weight Biopolymers by Different Plot Methods. Chia Gum Case. Journal of Polymer and Biopolymer Physics Chemistry. 2018, 6 (1), 13-25. Available online at http://pubs.sciepub.com/jpbpc/6/1/2
[8] Gao, S.; Holkar, A.; Srivastava, S. Protein -Polyelectrolyte Complexes and Micellar Assemblies. Polymers 2019, 11, 1097. https://doi.org/10.3390/polym11071097.
[9] Park J. W., Baik B. S. et al. The role of hyaluronic acid, chitosan, and calcium sulfate and their combined effect on early bony consolidation in distraction osteogenesis of a canine model // J. Craniofac. Surg. – 2002. – Vol. 13. – P. 783-793.
[10] Kozlov G. V., Dolbin I. V. High molecular weight compounds. Series B, 2020. Vol. 44 No. 1. P. 115-118.
[11] J. M. Khakkulov, Z. Sh. Temirov, & Sh. E. Khalilov. (2021). Electrochemical Reduction of Macroiones As A Surface-Active Nanocoating And Nanocomposites. The American Journal of Applied Sciences, 3 (06), 34–43. https://doi.org/10.37547/tajas/Volume03Issue06-06
[12] Meenesh R. Singh, Youngkook Kwon, Yanwei Lum, Joel W. Ager, and Alexis T. Bell. Hydrolysis of Electrolyte Cations Enhances the Electrochemical Reduction of CO2 over Ag and Cu. https://doi.org/10.1021/jacs.6b07612
[13] Zhen Yao, Shao-jie Liu, Fei Lv, Kun Cao., Determination of Mark–Houwink parameters of ethylene–norbornene copolymers and molecular characteristics estimation. https://doi.org/10.1002/app.28498
[14] Capitani, M. I., Corzo-Rios, L. J., Chel-Guerrero, L. A., BetancurAncona, D. A., Nolasco, S. M., & Tomás, M. C. (2015). Rheological properties of aqueous dispersions of chia (Salvia hispanica L.) mucilage. Journal of food engineering, 149, 70-77.
[15] Masuelli, M. A. 2014. Mark-Houwink parameters for aqueoussoluble polymers and biopolymers at various temperatures. J. Pol. Biopol. Phys. Chem., 2, 2, 37-43.
Cite This Article
  • APA Style

    Khakkulov Jakhongir Mardonovich, Kholmuminov Abdufatto Akhatovich. (2023). Polyelektrolite Solutions and Molecular Descriptions of Biopolymer Macroions. American Journal of Modern Physics, 11(6), 92-94. https://doi.org/10.11648/j.ajmp.20221106.11

    Copy | Download

    ACS Style

    Khakkulov Jakhongir Mardonovich; Kholmuminov Abdufatto Akhatovich. Polyelektrolite Solutions and Molecular Descriptions of Biopolymer Macroions. Am. J. Mod. Phys. 2023, 11(6), 92-94. doi: 10.11648/j.ajmp.20221106.11

    Copy | Download

    AMA Style

    Khakkulov Jakhongir Mardonovich, Kholmuminov Abdufatto Akhatovich. Polyelektrolite Solutions and Molecular Descriptions of Biopolymer Macroions. Am J Mod Phys. 2023;11(6):92-94. doi: 10.11648/j.ajmp.20221106.11

    Copy | Download

  • @article{10.11648/j.ajmp.20221106.11,
      author = {Khakkulov Jakhongir Mardonovich and Kholmuminov Abdufatto Akhatovich},
      title = {Polyelektrolite Solutions and Molecular Descriptions of Biopolymer Macroions},
      journal = {American Journal of Modern Physics},
      volume = {11},
      number = {6},
      pages = {92-94},
      doi = {10.11648/j.ajmp.20221106.11},
      url = {https://doi.org/10.11648/j.ajmp.20221106.11},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajmp.20221106.11},
      abstract = {Molecular mass characteristics of samples of ionic biopolymers, including chitosan and fibroin, the manifestation of physical conditions depending on the concentration of macroions, and hydrodynamic, rheological methods were used in the implementation of these studies. These processes depend on the fact that ionic polymers exhibit viscosity in relation to their molecular mass and are sensitive to the effects of the electric field at the expense of ionogenic groups. In order to determine this, the results of studies on the molecular characteristics of basic polymer objects were discussed. When polyelectrolytes are affected by external forces, including mechanical or electrical stresses, gradient fields are created, and macroions move along the lines of force of these fields. Such fields are observed, for example, when a liquid flows from a capillary under mechanical pressure, when the liquid is turned into a stable laminar flow using a rotor, or when ions and macroions move towards the poles (electrodes) during electrophoresis and electrolysis. In general, in the gradient field created under the influence of mechanical influence, the macroions move along the lines of force in rotation and advance, while in the gradient field created under the influence of electric voltage, the functional groups of macroions move towards the anode or cathode as anions or cations. The reason for the choice of poles is the sensitivity of anions or cations to the effect of an electric field.},
     year = {2023}
    }
    

    Copy | Download

  • TY  - JOUR
    T1  - Polyelektrolite Solutions and Molecular Descriptions of Biopolymer Macroions
    AU  - Khakkulov Jakhongir Mardonovich
    AU  - Kholmuminov Abdufatto Akhatovich
    Y1  - 2023/01/10
    PY  - 2023
    N1  - https://doi.org/10.11648/j.ajmp.20221106.11
    DO  - 10.11648/j.ajmp.20221106.11
    T2  - American Journal of Modern Physics
    JF  - American Journal of Modern Physics
    JO  - American Journal of Modern Physics
    SP  - 92
    EP  - 94
    PB  - Science Publishing Group
    SN  - 2326-8891
    UR  - https://doi.org/10.11648/j.ajmp.20221106.11
    AB  - Molecular mass characteristics of samples of ionic biopolymers, including chitosan and fibroin, the manifestation of physical conditions depending on the concentration of macroions, and hydrodynamic, rheological methods were used in the implementation of these studies. These processes depend on the fact that ionic polymers exhibit viscosity in relation to their molecular mass and are sensitive to the effects of the electric field at the expense of ionogenic groups. In order to determine this, the results of studies on the molecular characteristics of basic polymer objects were discussed. When polyelectrolytes are affected by external forces, including mechanical or electrical stresses, gradient fields are created, and macroions move along the lines of force of these fields. Such fields are observed, for example, when a liquid flows from a capillary under mechanical pressure, when the liquid is turned into a stable laminar flow using a rotor, or when ions and macroions move towards the poles (electrodes) during electrophoresis and electrolysis. In general, in the gradient field created under the influence of mechanical influence, the macroions move along the lines of force in rotation and advance, while in the gradient field created under the influence of electric voltage, the functional groups of macroions move towards the anode or cathode as anions or cations. The reason for the choice of poles is the sensitivity of anions or cations to the effect of an electric field.
    VL  - 11
    IS  - 6
    ER  - 

    Copy | Download

Author Information
  • "Physics of Semiconductors and Polymers" Department, Faculty of Physics, National University of Uzbekistan Named After M. Ulugbek, Tashkent, Republic of Uzbekistan

  • "Physics of Semiconductors and Polymers" Department, Faculty of Physics, National University of Uzbekistan Named After M. Ulugbek, Tashkent, Republic of Uzbekistan

  • Sections