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Refractory Concretes from Waste of Kovdor Mining and Processing Plant by Magnesium Phosphate Cement

Received: 30 August 2021     Accepted: 18 September 2021     Published: 29 November 2021
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Abstract

This work is aimed at using the technogenic raw materials of the Kovdorsky GOK for the production of refractory materials. Currently, many researchers are engaged in the development of technologies for unshaped materials. The most demanded among them are refractory concrete. They are able to set and harden at low temperatures with the formation of structures that retain their characteristics when heated. In our work, concretes were obtained from a briquette based on forsterite concentrate obtained from the waste of the Kovdorsky GOK. Magnesium phosphate cement was used as a binder. As a result of the research, the grain composition of the charge was selected, the ratio of filler and binder to improve the structural properties of concrete was found, the effects of the composition and the temperature of heat treatment of concretes on the physical and technical properties were shown. Concretes have the following characteristics: bulk density 2170-2260 kg / m3, strength up to 50 MPa (at 25°C), volume change after heat treatment at 450-1000°C 1-2%. Recovering the waste of the Kovdorsky GOK by manufacture of concrete will lead to a qualitatively new use of non-renewable natural resources, reduce the rate of depletion of mineral raw materials in the subsoil, eliminate sources of environmental pollution and restore land occupied by waste.

Published in American Journal of Environmental Protection (Volume 10, Issue 6)
DOI 10.11648/j.ajep.20211006.14
Page(s) 149-157
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2021. Published by Science Publishing Group

Keywords

Forsterite Concentrate, Magnesium Phosphate Cement, Refractory Concrete

References
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[3] Orlov A., Chernykh T. Research of water resistance and heat resistance of magnesium phosphate cements. Procedia Engineering 2016; 150: 1623-36. DOI: 10.1016/j.proeng.2016.07.140.
[4] Sudakas L. G. Phosphate binders. SPb: RIA "Quintet"; 2008: 260 p.
[5] Makio Kinoshita, Kiyoshi Itatani, Akira Kishioka Thermal analysis of Mg(H2PO4)2∙2H2O under various reduced pressures. Gypsum and Lime 1982; 177: 13-19.
[6] Soudee E. Liants phosphomagnesiens – mecanique de prise et durabilite: diss. Doctorat. Lyon 1999: 266. http://theses.insa-lyon.fr/publication/1999ISAL0049/these.pdf.
[7] Bamford C. H., Tipper C. F. H. Reactions in the solid state. Amsterdam: Elsevier 1980: 340 p.
[8] Walling S. A., Provis J. L. Magnesia- Based Cements: A Journey of 150 Years, and Cements for the Future. Chem. Rev. 2016; 116: 4170-204. DOI: 10.1021/acs.chemrev.5b00463.
[9] GOST 2642.3-2014 Refractories and refractory raw materials. Methods for determination of silicon dioxide. M.: Standartinform; 2015.
[10] GOST 2642.8-2017 Refractories and refractory raw materials. Methods for determination of magnesium oxide. M.: Standartinform; 2017.
[11] GOST 2642.5-2016 Refractories and refractory raw materials. Methods for the determination of iron (III) oxide. M.: Standartinform; 2016.
[12] GOST 2642.7-2017 Refractories and refractory raw materials. Methods for determination of calcium oxide. M.: Standartinform; 2017.
[13] GOST 2642.2-2014 Refractories and refractory raw materials. Determination of loss on ignition. M.: Standartinform; 2015.
[14] GOST 53657-2009 Iron ores, concentrates and pallets. Method of determination of bivalence iron calculated as ferrous oxide. M.: Standartinform; 2010.
[15] GOST 27707-2007 Unshaped refractories. Methods for determining the grain size composition. M.: Standartinform; 2008.
[16] GOST10180-2012 Concretes. Methods for strength determination using reference specimens. M.: Standartinform; 2013.
[17] GOST2409-2014 Refractories. Methods for determination of bulk density, apparent and true porosity, water absorption. M.: Standartinform; 2015.
[18] GOST 5402.1-2000 Refractory products with a true porosity of less than 45%. Method for determination of permanent change in dimensions on heating.
[19] Illarionov I. E., Strelnikov I. A., Gartfelder V. A., Korolev A. V., Shalunov E. P., Hilmanshina T. R. Development and application of metal-phosphate binders for obtaining forming, rod and thermal insulation mixtures and coatings. The theory and process engineering of metallurgical production 2018; 27 [4]: 4-11.
[20] L. G. Gardner, S. A. Walling, C. L. Corchill, S. A. Bernal, V. Lejeune, M. C. Stennet, J. I. Provis, N. C. Hyatt Temperature transformation of blended magnesium potassium phosphate cement binders. Cement and Concrete research 141 (2021) 106332.
[21] S. Hing, C. Wu Preparation of Magnesium Phosphate Cement and Application in Concrete Repair. MATEC Web of Conferences 142, 02007 (2018) https://doi.org/10.1051/matecconf/201814202007.
[22] X. Tao, J. Liu, M. Wang Effect of Heat-treatment on Microstructure and Mechanical Properties of Magnesium Phosphate Cement. Key Engineering Materials, Vol. 680, pp. 447-450 doi: 10.4028/wwwscientific.net/KEM.680.447.
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  • APA Style

    Olga Belogurova, Marina Savarina, Tatyana Sharai. (2021). Refractory Concretes from Waste of Kovdor Mining and Processing Plant by Magnesium Phosphate Cement. American Journal of Environmental Protection, 10(6), 149-157. https://doi.org/10.11648/j.ajep.20211006.14

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    ACS Style

    Olga Belogurova; Marina Savarina; Tatyana Sharai. Refractory Concretes from Waste of Kovdor Mining and Processing Plant by Magnesium Phosphate Cement. Am. J. Environ. Prot. 2021, 10(6), 149-157. doi: 10.11648/j.ajep.20211006.14

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    AMA Style

    Olga Belogurova, Marina Savarina, Tatyana Sharai. Refractory Concretes from Waste of Kovdor Mining and Processing Plant by Magnesium Phosphate Cement. Am J Environ Prot. 2021;10(6):149-157. doi: 10.11648/j.ajep.20211006.14

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  • @article{10.11648/j.ajep.20211006.14,
      author = {Olga Belogurova and Marina Savarina and Tatyana Sharai},
      title = {Refractory Concretes from Waste of Kovdor Mining and Processing Plant by Magnesium Phosphate Cement},
      journal = {American Journal of Environmental Protection},
      volume = {10},
      number = {6},
      pages = {149-157},
      doi = {10.11648/j.ajep.20211006.14},
      url = {https://doi.org/10.11648/j.ajep.20211006.14},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajep.20211006.14},
      abstract = {This work is aimed at using the technogenic raw materials of the Kovdorsky GOK for the production of refractory materials. Currently, many researchers are engaged in the development of technologies for unshaped materials. The most demanded among them are refractory concrete. They are able to set and harden at low temperatures with the formation of structures that retain their characteristics when heated. In our work, concretes were obtained from a briquette based on forsterite concentrate obtained from the waste of the Kovdorsky GOK. Magnesium phosphate cement was used as a binder. As a result of the research, the grain composition of the charge was selected, the ratio of filler and binder to improve the structural properties of concrete was found, the effects of the composition and the temperature of heat treatment of concretes on the physical and technical properties were shown. Concretes have the following characteristics: bulk density 2170-2260 kg / m3, strength up to 50 MPa (at 25°C), volume change after heat treatment at 450-1000°C 1-2%. Recovering the waste of the Kovdorsky GOK by manufacture of concrete will lead to a qualitatively new use of non-renewable natural resources, reduce the rate of depletion of mineral raw materials in the subsoil, eliminate sources of environmental pollution and restore land occupied by waste.},
     year = {2021}
    }
    

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  • TY  - JOUR
    T1  - Refractory Concretes from Waste of Kovdor Mining and Processing Plant by Magnesium Phosphate Cement
    AU  - Olga Belogurova
    AU  - Marina Savarina
    AU  - Tatyana Sharai
    Y1  - 2021/11/29
    PY  - 2021
    N1  - https://doi.org/10.11648/j.ajep.20211006.14
    DO  - 10.11648/j.ajep.20211006.14
    T2  - American Journal of Environmental Protection
    JF  - American Journal of Environmental Protection
    JO  - American Journal of Environmental Protection
    SP  - 149
    EP  - 157
    PB  - Science Publishing Group
    SN  - 2328-5699
    UR  - https://doi.org/10.11648/j.ajep.20211006.14
    AB  - This work is aimed at using the technogenic raw materials of the Kovdorsky GOK for the production of refractory materials. Currently, many researchers are engaged in the development of technologies for unshaped materials. The most demanded among them are refractory concrete. They are able to set and harden at low temperatures with the formation of structures that retain their characteristics when heated. In our work, concretes were obtained from a briquette based on forsterite concentrate obtained from the waste of the Kovdorsky GOK. Magnesium phosphate cement was used as a binder. As a result of the research, the grain composition of the charge was selected, the ratio of filler and binder to improve the structural properties of concrete was found, the effects of the composition and the temperature of heat treatment of concretes on the physical and technical properties were shown. Concretes have the following characteristics: bulk density 2170-2260 kg / m3, strength up to 50 MPa (at 25°C), volume change after heat treatment at 450-1000°C 1-2%. Recovering the waste of the Kovdorsky GOK by manufacture of concrete will lead to a qualitatively new use of non-renewable natural resources, reduce the rate of depletion of mineral raw materials in the subsoil, eliminate sources of environmental pollution and restore land occupied by waste.
    VL  - 10
    IS  - 6
    ER  - 

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Author Information
  • Tananaev Institute of Chemistry, Subdivision of the Federal Research Centre “Kola Science Centre of the Russian Academy of Sciences”, Apatity, Murmansk Region, Russia

  • Tananaev Institute of Chemistry, Subdivision of the Federal Research Centre “Kola Science Centre of the Russian Academy of Sciences”, Apatity, Murmansk Region, Russia

  • Tananaev Institute of Chemistry, Subdivision of the Federal Research Centre “Kola Science Centre of the Russian Academy of Sciences”, Apatity, Murmansk Region, Russia

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